MATEC Web Conf.
Volume 321, 2020The 14th World Conference on Titanium (Ti 2019)
|Number of page(s)||22|
|Section||Extraction and Powder Production|
|Published online||12 October 2020|
Thermodynamic Investigation of Titanium Hydride Formation from Reduction of Titanium (Ⅳ) Chloride with Magnesium Hydride in Presence of Hydrogen Atmosphere
1 School of Materials and Mineral Resources Engineering, Universiti Sains Malaysia, Nibong Tebal
2 Mineral Research Centre, Mineral and Geoscience Department Malaysia, Ipoh, Perak
3 Nanomaterials Research Group, School of Chemical Sciences, Universiti Sains Malaysia, Penang, Malaysia
1 Corresponding author: firstname.lastname@example.org
Thermodynamic assessment and experimental investigation for formation of titanium hydride (TiH2) from reduction of titanium tetrachloride (TiCl4) with magnesium hydride (MgH2) were carried out under hydrogen atmosphere. In this method, TiH2 production at low temperature was investigated, which can be used for further dehydrogenation process in titanium powder metallurgy. The effects of temperature, time, amount of titanium trifluoride (TiF3) as catalyst, and ball milling time of MgH2 on reduction process were evaluated. The range of each parameters were set to 250-350°C for temperature, 2-4 hr for reaction time, 4-10 wt% for TiF3, and 1-2 hr for ball milling time. The phase transformations after reduction process were studied by X-ray diffraction (XRD) and energy-dispersive X-ray (EDX) analyziz. The morphology of powders was analyzed by scanning electron microscope (SEM). The results showed that titanium trichloride (TiCl3) was formed as major product in experiments for the above conditions. However, with increasing the reaction time above 10hr, characterization study of the final products confirmed the formation of TiH2 as major product. Our findings indicated that producing of TiH2 from reduction of TiCl4 with MgH2 at low temperature was feasible and could lead to low cost synthesis method for TiH2 for titanium powder production.
Key words: Powder Metallurgy / Titanium / Titanium Hydride / Thermodynamic assessment
© The Authors, published by EDP Sciences, 2020
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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