| Issue |
MATEC Web Conf.
Volume 96, 2017
III International Symposium “Fundamental Aspects of Rare-Earth Elements Exploration, Mining and Separation and Modern Materials Engineering” (REE-2016)
|
|
|---|---|---|
| Article Number | 00002 | |
| Number of page(s) | 6 | |
| DOI | https://doi.org/10.1051/matecconf/20179600002 | |
| Published online | 19 January 2017 | |
Acid Activation of Natural Zeolite with High Content of Iron Oxides in Creation of Selective Sorbents and Catalysts
1 LLP “Kazatomprom-Sorbent”, Almaty, Kazakhstan
2 JSC “A.B. Bekturov Institute of Chemical Sciences”, Almaty, Kazakhstan
* Corresponding author: kkairati@mail.ru
The paper studies the influence of the nature of modifying acids (mineral, organic and heteropolyacids), and their combination on the composition and structure of the iron oxide rich clinoptilolit from Shankanay field in Kazakhstan for creation of selective catalysts in hydracarbon processing and sorbents for extracting ions of lanthanide and actinide elements. It is shown that sequential processing of natural zeolite in optimal conditions, by hydrochloric and sulfosalicylic acids lead to intensive decationization and dealumination, as well as maximum removal of iron ions from the zeolite framework without destroying it. It is found that the combination of activated clinoptilolite with hydrochloric acid and phosphotungstic heteropolyacid contributes to obtain catalyst system with high surface area and acidity.
© The Authors, published by EDP Sciences, 2017
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