Issue |
MATEC Web of Conferences
Volume 60, 2016
2016 3rd International Conference on Chemical and Biological Sciences
|
|
---|---|---|
Article Number | 01005 | |
Number of page(s) | 6 | |
Section | Materials science and Application | |
DOI | https://doi.org/10.1051/matecconf/20166001005 | |
Published online | 08 June 2016 |
Oscillatory reactions in the acetone-glucose-sodium bromate-sulfuric acid system with a tetraazamacrocyclic copper (II) complex as a catalyst
Institute of Applied Chemistry, East China Jiaotong University, 330013, Nanchang, P.R. China
* Corresponding author:hulin21@hotmail.com
The behavior of glycolysis concerning the biochemical reaction was thought to be similar to the oscillatory reaction with glucose being the substrate. The objective of this research is to find a new oscillatory system and study its relevant properties, so new Cu (II)-catalyzed oscillating reaction involved glucose and acetone as the double substrates was investigated systematically. As a function of reaction temperature and concentration of glucose, bromate, and acetone, the features in this novel oscillation system was studied. The results showed that the activation energy reached up to 90.839 KJ/mol and the oxidized product of the double substrates provided the impetus in the course of the new oscillating reaction. A tentative mechanism was considered on the basis of FNK.
© Owned by the authors, published by EDP Sciences, 2016
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Current usage metrics show cumulative count of Article Views (full-text article views including HTML views, PDF and ePub downloads, according to the available data) and Abstracts Views on Vision4Press platform.
Data correspond to usage on the plateform after 2015. The current usage metrics is available 48-96 hours after online publication and is updated daily on week days.
Initial download of the metrics may take a while.