Issue |
MATEC Web Conf.
Volume 130, 2017
The International Conference on Composite Material, Polymer Science and Engineering (CMPSE2017)
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Article Number | 07002 | |
Number of page(s) | 5 | |
Section | Synthesis and evaluation of composite materials | |
DOI | https://doi.org/10.1051/matecconf/201713007002 | |
Published online | 25 October 2017 |
Effect of polymer concentration on the lifetime and transmittance behavior of a self-oscillating polymer chain with a high lower critical solution temperature
Research Institute for Sustainable Chemistry, ISC, National Institute of Advanced Industrial Science and Technology, AIST, Central 5-2, 1-1-1 Higashi, Tsukuba 305-8565, Japan
a Corresponding author: y-hara@aist.go.jp
In this study, we investigated the lifetime and self-oscillating behavior of a polymer chain with a high lower critical solution temperature (LCST). The polymer chain comprised 4-vinyl-4´-methyl-2,2´-bipyridinebis(2,2´-bipyridine)bis(hexafluorophosphate) ruthenium as catalyst for the Belousov–Zhabotinsky reaction and N-ethylacrylamide as the polymer main-chain with a high LCST when compared to N-isopropylacrylamide. We demonstrated that the self-oscillating behavior was significantly affected by the polymer concentration and measuring temperature. Moreover, we established that the lifetime of the transmittance self-oscillation can be predicted from the polymer concentration and measuring temperature.
© The authors, published by EDP Sciences, 2016
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (http://creativecommons.org/licenses/by/4.0/).
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