MATEC Web of Conferences
Volume 14, 2014EUROSUPERALLOYS 2014 – 2nd European Symposium on Superalloys and their Applications
|Number of page(s)||6|
|Section||Posters: Deformation and Damage Mechanisms I: Creep|
|Published online||08 October 2014|
Multi-scale modelling of Suzuki segregation in γ′ precipitates in Ni and Co-base superalloys
Department of Materials Engineering, Indian Institute of Science, Bangalore 560012, India
a Corresponding author: email@example.com
The high temperature strength of alloys with (γ + γ′) microstructure is primarily due to the resistance of the ordered precipitate to cutting by matrix dislocations. Such shearing requires higher stresses since it involves the creation of a planar fault. Planar fault energy is known to be dependent on composition. This implies that the composition on the fault may be different from that in the bulk for energetic reasons. Such segregation (or desegregation) of specific alloying elements to the fault may result in Suzuki strengthening which has not been explored extensively in these systems. In this work, segregation (or desegregation) of alloying elements to planar faults was studied computationally in Ni3(Al,Ti) and Co3(W,Al) type γ′ precipitates. The composition dependence of APB energy and heat of mixing were evaluated from first principle electronic structure calculations. A phase field model incorporating the first principles results, was used to simulate the motion of an extended superdislocation under stress concurrently with composition evolution. Results reveal that in both systems, significant (de)segregation occurs on equilibration. On application of stress, solutes were dragged along with the APB in some cases. Additionally, it was also noted the velocity of the superdislocation under an applied stress is strongly dependent on atomic mobility (i.e. diffusivity).
© Owned by the authors, published by EDP Sciences, 2014
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