Production of Lactic Acid from Empty Fruit Bunch of Palm Oil Using Catalyst of Barium Hydroxide

Department of Chemical Engineering, Faculty of Industrial Technology, Institute of Technology Bandung, 40132 Bandung, Indonesia

^* Corresponding author: cbr@che.itb.ac.id

Abstract

Lactic Acid as a platform chemical has broad application in various industries, especially in the production of Poly Lactic Acid (PLA) for biodegradable plastic. Empty fruit bunch (EFB), abundant by product from palm oil mill industry, is one of potential feedstock to be used in the production of lactic acid from lignocellulose biomass. EFB contains high cellulose and hemicellulose about 37– 59.7% w/w and 16–28% w/w, respectively. The aim of this paper is to study the effects of the operating conditions, such as temperature, reaction time, biomass loading, and catalyst concentration on the yield of lactic acid using barium hydroxide as alkaline catalyst. EFB pretreatment with steam explosion was applied to remove lignin content. The results showed that pretreatment reduced the lignin content from 22.66% to 9.69% w/w. Meanwhile, hemicellulose and cellulose increased from 14.40% to 16.40% w/w and 29.37% to 63.57% w/w, respectively. The highest yield of lactic acid was 21.57% C-mol, achieved by using 0.25 M Ba(OH)₂ as the catalyst, with 5% w/v biomass loading, temperature 240°C, during 4 h reaction times. The yield was approximately equal to yield of lactic acid (~ 20%) compared with Pb²⁺ as the catalyst for EFB conversion although the later catalyst produced fewer by products during conversion.