Palm H-FAME Production through Partially Hydrogenation using Nickel/Carbon Catalyst to Increase Oxidation Stability

Chemical Engineering Department, Faculty of Engineering, University of Indonesia, Depok 16424, Indonesia

^* Corresponding author: bambanghs@che.ui.ac.id

Abstract

One of the methods to improve the oxidation stability of palm biodiesel is through partially hydrogenation. The production using Nickel/Carbon catalyst to speed up the reaction rate. Product is called Palm H-FAME (Hydrogenated FAME). Partial hydrogenation breaks the unsaturated bond on FAME (Fatty Acid Methyl Ester), which is a key component of the determination of oxidative properties. Changes in FAME composition by partial hydrogenation are predicted to change the oxidation stability so it does not cause deposits that can damage the injection system of diesel engine, pump system, and storage tank. Partial hydrogenation is carried out under operating conditions of 120 °C and 6 bar with 100:1, 100:3, 100:5, 100:10 % wt catalyst in the stirred batch autoclave reactor. H-FAME synthesis with 100:5 % wt Ni/C catalyst can decrease the iodine number which is the empirical measure of the number of unsaturated bonds from 91.78 to 82.38 (g-I₂/100 g) with an increase of oxidation stability from 585 to 602 minutes.