MATEC Web Conf.
Volume 243, 2018XIV International Workshop High Energy and Special Materials: Demilitarization, Antiterrorism and Civil Application (HEMs-2018)
|Number of page(s)||6|
|Published online||05 December 2018|
Temperature-programmed surface reactions of methanol and dimethyl ether on bifunctional catalysts for the direct synthesis of dimethyl ether from syngas
1 National Research Tomsk State University, 634050, Tomsk, Russia
2 Siberian Research Institute of Agriculture and Peat – branch of the Siberian Federal Scientific Center of Agro-Bio Technologies of the Russian Academy of Sciences, 634050, Tomsk, Russia
3 Westfalische Wilhelms-Universitat Munster, Institute of Biochemistry, Munster, Germany
* Corresponding author: email@example.com
Dimethyl ether (DME) can be used as a replacement for diesel fuel in transportation. The catalytic effectiveness of bifunctional catalysts for DME one-stage synthesis from carbon monoxide and hydrogen was estimated in the paper. Bifunctional catalysts CuZnAl/HZSM-5, CuZnAlCr/HZSM-5, and CuZnAlZr/HZSM-5 were obtained by physical mixing of CuZnAl(Cr/Zr)– Ох and HZSM-5 components and were characterized by BET, X-ray diffraction, and temperatureprogrammed surface reaction methods. Based on the TPSR results, the mechanism of the interaction of methanol and DME with the surface of the bifunctional catalyst was studied. It was found that the temperature range of the greatest catalytic activity was 240–260 °С.
© The Authors, published by EDP Sciences, 2018
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