| Issue |
MATEC Web Conf.
Volume 242, 2018
International Conference on Advanced Functional Materials and Composites (ICAFMC2018)
|
|
|---|---|---|
| Article Number | 01005 | |
| Number of page(s) | 5 | |
| Section | Carbon Composites | |
| DOI | https://doi.org/10.1051/matecconf/201824201005 | |
| Published online | 05 December 2018 | |
Modeling of the Formation Processes of Nanocomposite Coatings by the Electrocodeposition
1 Institute of Mechanics, Udmurt Federal Research Center of the Ural Branch of the Russian Academy of Science, Izhevsk, Russia
2 Kalashnikov Izhevsk State Technical University, Izhevsk, Russia
a Corresponding author: Vakhrushev-a@yandex.ru
The coupled mathematical model of electrocodeposition process on the rotating cylinder electrode is presented. Low Reynolds k-e model with Abe-Kondoh-Nagano damping functions is used to describe mass transport of electrolyte. The cathodic and anodic processes are described by the tertiary current distribution theory. Mass transfer of electrolyte ions is described by diffusion-convection equation and is studied throughout the volume of the electrolyte cell. The simulation of electrocodeposition of Cu-Al2O3 nanoparticles on rotating cylinder electrode of are presented. It is found that the unsteady diffusion layer is formed close to the rotating electrode surface. Also it was found that the sign of the zeta potential of nanoparticles has a decisive influence on the possibility of forming the composite coatings. The results of mathematical modelling are in good agreement with the experimental data.
© The Authors, published by EDP Sciences, 2018
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