| Issue |
MATEC Web Conf.
Volume 142, 2018
International Conference on Materials Applications and Engineering 2017 (ICMAE2017)
|
|
|---|---|---|
| Article Number | 01010 | |
| Number of page(s) | 9 | |
| Section | Chemical Materials and Chemical Syntheses | |
| DOI | https://doi.org/10.1051/matecconf/201814201010 | |
| Published online | 08 January 2018 | |
Synthesis and Luminescence Properties of the Binary/Ternary Complex of Samarium Ion with Phenacylmethyl P-Tolyl Sulfoxide and Benzoic Acid
College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, People's Republic of China
* Corresponding author: nmglwx@163.com
A new ligand phenacylmethyl p-tolyl sulfoxide (denoted as L1) has been synthesized by an asymmetric synthesis method. Its novel binary complex Sm(L1)7·(ClO4)3·6H2O, and ternary complex Sm(L1)6·(L2)·(ClO4)2·6H2O (benzoic acid denoted as L2) have been synthesized. The structure and composition of the samarium complexes characterized by elemental analysis, molar conductivity, IR, UV, and 1HNMR. Additionally, fluorescence spectra measurements shows that the complexes display stronger fluorescence intensity in solid state, indicating the ligands could efficiently transfer the energy to Sm3+ ions in the complexes. The ternary complex has stronger fluorescence intensity than the binary complex.
© The Authors, published by EDP Sciences, 2018
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (http://creativecommons.org/licenses/by/4.0/).
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