| Issue |
MATEC Web Conf.
Volume 141, 2017
The Fifth International Youth Forum “Smart Grids 2017”
|
|
|---|---|---|
| Article Number | 01026 | |
| Number of page(s) | 5 | |
| DOI | https://doi.org/10.1051/matecconf/201714101026 | |
| Published online | 12 December 2017 | |
Influence of Cu(NO3)2 initiation additive in two-stage mode conditions of coal pyrolytic decomposition
1
National Research Tomsk Polytechnic University, 634050 Tomsk, Russia
2
Boreskov Institute of Catalysis SB RAS, 630090 Novosibirsk, Russia
* Corresponding author: laryk070@gmail.com
Two-stage process (pyrolysis and oxidation) of brown coal sample with Cu(NO3)2 additive pyrolytic decomposition was studied. Additive was introduced by using capillary wetness impregnation method with 5% mass concentration. Sample reactivity was studied by thermogravimetric analysis with staged gaseous medium supply (argon and air) at heating rate 10 °C/min and intermediate isothermal soaking. The initiative additive introduction was found to significantly reduce volatile release temperature and accelerate thermal decomposition of sample. Mass-spectral analysis results reveal that significant difference in process characteristics is connected to volatile matter release stage which is initiated by nitrous oxide produced during copper nitrate decomposition.
© The Authors, published by EDP Sciences, 2017
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (http://creativecommons.org/licenses/by/4.0/).
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