| Issue |
MATEC Web Conf.
Volume 67, 2016
International Symposium on Materials Application and Engineering (SMAE 2016)
|
|
|---|---|---|
| Article Number | 04002 | |
| Number of page(s) | 6 | |
| Section | Chapter 4 Surface Engineering and Coating Technology | |
| DOI | https://doi.org/10.1051/matecconf/20166704002 | |
| Published online | 29 July 2016 | |
Hydrogen Production by Catalytic Partial Oxidation of Coke Oven Gas in BaCo0.7Fe0.3-xZrxO3-δ Ceramic Membrane Reactors
1 School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China
2 State Key Laboratory of Advanced Special Steel, Shanghai University, Shanghai 200072, China
a hwcheng@shu.edu.cn
b luxg@shu.edu.cn
* Corresponding author: hwcheng@shu.edu.cn
The BaCo0.7Fe0.3-xZrxO3-δ (BCFZ, x = 0.04–0.12) mixed ionic–electronic conducting (MIEC) membranes were synthesized with a sol–gel method and evaluated as potential membrane reactor materials for the partial oxidation of coke oven gas (COG). The effect of zirconium content on the phase structure, microstructure and performance of the BCFZ membrane under He or COG atmosphere were systemically investigated. The BaCo0.7Fe0.24Zr0.06O3-δ membrane exhibited the best oxygen permeability and good operation stability, which could be a potential candidate of the membrane materials for hydrogen production through the partial oxidation of COG.
© The Authors, published by EDP Sciences, 2016
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Current usage metrics show cumulative count of Article Views (full-text article views including HTML views, PDF and ePub downloads, according to the available data) and Abstracts Views on Vision4Press platform.
Data correspond to usage on the plateform after 2015. The current usage metrics is available 48-96 hours after online publication and is updated daily on week days.
Initial download of the metrics may take a while.