Electrical characterization of aeronautical nanocomposites supported by Tunneling AFM (TUNA)

¹ Department of Information and Electrical Engineering and Applied Mathematics, University of Salerno, Via Giovanni Paolo II, 132, 84084, Fisciano ( SA), Italy
² Department of Industrial Engineering, University of Salerno, Via Giovanni Paolo II, 132, 84084, Fisciano ( SA), Italy
³ University of Dayton, 300 College Park, Dayton Ohio, 45440, USA

^* e-mail: plamberti@unisa.it

Abstract

Epoxy nanocomposites fulfill tight and compelling industrial requirements in the field of structural material for aeronautical applications. In this paper the development and characterization of nanocomposites obtained by filling tetrafunctional epoxy resin (tetraglycidyl methylene dianiline cured with the aromatic diamine 4,4’-diaminodiphenylsulfone, named T20BD) with carbon nanofibers (CNF) is discussed. A filler amount ranging from 0.05% to 2%wt is considered. The DC volume conductivity and the dielectric characteristics (ϵ’) of the nanocomposites in the frequency range 100Hz-1MHz are analyzed and compared with those of the pure resin. Atomic force microscopy, mapping the local topography by means of tunneling effect, is used for recording the electrical percolation path for nanocomposites. In particular, the case 1.3wt% of CNF filled nanocomposites that exhibits a stable behavior of the conductivity in the full investigated frequency range, is here reported. The developed filled epoxy used in carbon fiber reinforced composites, shows enhanced electrical properties leading to better electromagnetic (EM) performances in EM coatings, EM shields and filters or radar absorber materials (RAMs).