Issue |
MATEC Web Conf.
Volume 340, 2021
VII International Russian - Kazakhstan Conference “Chemical Technologies of Functional Materials” (RKFM 2021)
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Article Number | 01026 | |
Number of page(s) | 8 | |
DOI | https://doi.org/10.1051/matecconf/202134001026 | |
Published online | 08 July 2021 |
Hydrogenation of benzene and toluene over supported rhodium and rhodium-gold catalysts
1 Al-Farabi Kazakh National University, Almaty, Kazakhstan
2 L.N. Gumilyov Eurasian National University, Nur-Sultan, Kazakhstan
Rhodium and rhodium-gold catalysts supported on amorphous aluminosilicates (ASA), titanium dioxide (rutile, TiO2) was prepared in two different ways: absorption and colloidal method. The catalysts were characterized by an inductively coupled plasma optical emission spectrometer (ICP-OES), transmission electron microscopy (TEM) and X-ray diffraction (XRD). The activity and selectivity of the prepared catalysts were tested by the hydrogenation of benzene and toluene. Hydrogenation was conducted at a pressure of 4 MPa and a temperature 80 °C. The bimetallic Rh-Au/ASA catalyst prepared by the absorption method showed higher activity and selectivity in benzene hydrogenation reaction, the same catalyst prepared by the colloidal method demonstrated lower selectivity.
© The Authors, published by EDP Sciences, 2021
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