Catalytic Dehydrofluorination of Hydrofluoroalkanes to Fluorinated Olifein Over Ni/AlF₃ Catalysts

¹ School of Chemistry and Chemical Engineering, Hubei Polytechnic University, 435003, Hubei, China
² School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China
³ Dyson school of design engineering, Imperial college London, London W2 1PG, UK

^a Corresponding author: deng29606@sina.com

Abstract

The hydrofluoric acid-resisting aluminum compounds (AlF₃, AlPO₄, AlN) supported with Ni catalyst were prepared by the wetness impregnation and tested for dehydrofluorination of hydrofluoroalkane to synthesize fluoroolefins. It is found that Ni/AlF₃ catalyst has the best catalytic performance, CF₃CFH₂ conversion of 29.3% after the reaction at 430 °C for 30 h, CF₂HCH3 conversion of 31.8% after the reaction at 250 °C for 30 h, respectively. Comparatively, dehydrofluorination temperature of CF₃CFH₂ is higher than CF₂HCH₃ over the aluminum compounds catalyst, and the activity of catalysts is related with Lewis acidity. For the aluminum compounds catalyst, addition of Ni had promoted the activity and stability of Lewis acidic catalysts, it is attributed to synergistic catalysis of Lewis acid sites and Ni.