| Issue |
MATEC Web Conf.
Volume 142, 2018
International Conference on Materials Applications and Engineering 2017 (ICMAE2017)
|
|
|---|---|---|
| Article Number | 01004 | |
| Number of page(s) | 7 | |
| Section | Chemical Materials and Chemical Syntheses | |
| DOI | https://doi.org/10.1051/matecconf/201814201004 | |
| Published online | 08 January 2018 | |
Two Water Stable Copper Metal-Organic Frameworks with Performance in the Electrocatalytic Activity for Water Oxidation
1
College of Science, China University of Petroleum, Qingdao, Shandong 266580, People’s Republic of China
2
Linyi jun cheng leather co., LTD, Linyi, Shandong 276000, People’s Republic of China
* Corresponding author: lmzhao@upc.edu.cn
Two novel water stable metal-organic frameworks, [Cu(L)·(4,4′-bipy)·(ClO4)]n (1), [Cu(L)·(phen)·(ClO4)·(H2O)]2 (2), have been constructed by HL=[5-Mercapto-1-methyl] tetrazole acetic acid and Cu (II) salt in the presence of assistant N-containing ligands. MOF 1 and MOF 2 with open CuII sites, resulting the framework 1 and 2 show electrocatalytic activity for water oxidation in alkaline solution. The electrochemical properties of complex for oxygen evolution reaction (OER) were evaluated by linear sweep voltammetry (LSV) and the Tafel slopes. Complex 1 has a higher LSV activity with a lower over potential of 1.54 V and a much higher increase in current density. Meanwhile, the Tafel slope of complex 1 (122.0 mV dec-1) is much lower than complex 2 (243.5 mV dec-1). This phenomenon makes complex 1 a promising porous material for electrocatalytic activity.
© The Authors, published by EDP Sciences, 2018
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 4.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (http://creativecommons.org/licenses/by/4.0/).
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