MATEC Web Conf.
Volume 101, 2017Sriwijaya International Conference on Engineering, Science and Technology (SICEST 2016)
|Number of page(s)||5|
|Section||Emerging Concepts in Chemical Process & Energy Engineering|
|Published online||09 March 2017|
Partial oxidation of methane to methanol over catalyst ZSM-5 from coal fly ash and rice husk ash
1 Agency for Assessment and Application of Technology, 10340 Jakarta, Indonesia
2 Department of Chemistry Faculty of Mathematics and Natural Science Universitas Indonesia, 16424 Depok, Indonesia
* Corresponding author: firstname.lastname@example.org
Methane is one of the greenhouse gases that can be converted into liquid fuels such as methanol to retain most of the energy of methane and produce a cleaner environment. The conversion of methane to methanol using ZMS-5 represents a breakthrough in the utilization of methane. However, material sources for zeolite synthesis as catalyst usually are pro-analysis grade materials, which are expensive. Therefore, in this research, coal fly ash and rice husk ash were used as raw materials for mesoporous ZSM-5 zeolite synthesis. First, coal fly ash and rice husk were subjected to pre-treatment to extract silicate (SiO44−) and aluminate (AlO45−) and impurities separation. The ZSM-5 zeolite was synthesized through hydrothermal treatment using two types of templates. After ZSM-5 was synthesized, it was modified with Cobalt through impregnation method. The catalytic activity of both ZSM-5 and Co/ZSM-5 zeolites as heterogeneous catalysts in partial oxidation of methane were preliminary tested and compared with that commercial one. The result showed that the zeolite catalyst ZSM-5 from fly ash coal and rice husk ash has the potential to be used as catalysts in the partial oxidation of methane to methanol.
© The Authors, published by EDP Sciences, 2017
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