MATEC Web Conf.
Volume 63, 20162016 International Conference on Mechatronics, Manufacturing and Materials Engineering (MMME 2016)
|Number of page(s)||4|
|Section||Mechatronic and Application Engineering|
|Published online||12 July 2016|
Adsorption/oxidation of sulfur-containing gases on nitrogen-doped activated carbon
College of Science, China University of Petroleum-Beijing, 102249 Beijing, China
a Corresponding author: email@example.com
Coconut shell-based activated carbon (CAC) was used for the removal of methyl mercaptan (MM). CAC was modified by urea impregnation and calcined at 450°C and 950°C. The desulfurization activity was determined in a fixed bed reactor under room temperature. The results showed that the methyl mercaptan adsorption/oxidation capacity of modified carbon caicined at 950°C is more than 3 times the capacity of original samples. On the other hand, the modified carbon caicined at 950°C also has a high capacity for the simultaneous adsorption/oxidation of methyl mercaptan and hydrogen sulfide.The introduce of basic nitrogen groups siginificantly increases the desulfurization since it can facilitate the electron transfer process between sulfur and oxygen. The structure and chemical properties are characterized using Boehm titration, N2 adsorption-desorption method, thermal analysis and elemental analysis. The results showed that the major oxidation products were dimethyl disulfide and methanesulfonic acid which adsorbed in the activated carbon.
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