MATEC Web of Conferences
Volume 3, 2013XXXIX JEEP – 39th Edition of the Joint European Days on Equilibrium Between Phases
|Number of page(s)||4|
|Published online||01 July 2013|
Determination of acid dissociation constants of some hydroxy schiff bases by pH-metric titration. application of the Hammett equation
Faculty of Science and Technology, Department of Industrial Chemistry, University of Biskra, 07000, Algeria
Ten compounds hydroxybases Schiff were synthesized from salicylaldehyde and the substituted aniline in the ortho, meta and para methyl groups, chloro and nitro. To study the effect of substituents on their acidities, the acid dissociation constants( Ka) of salicylideneaniline and some of their derivatives were determined by pH-metric titration. All Schiff bases were titrated with NaOH in mixtures of 60% dioxane-water and 60% ethanol-water at a constant ionic strength and a temperature of 25 °C. The calculated acidity constants, pKa values were evaluated in protonation –deprotanation mechanisms. The Hammett relationship linear type was applied to quantify the effects of substituents on the acidity of hydroxybases Schiff, and therefore a reaction constant, ρ is calculated.
© Owned by the authors, published by EDP Sciences, 2013
This is an Open Access article distributed under the terms of the Creative Commons Attribution License 2.0, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Current usage metrics show cumulative count of Article Views (full-text article views including HTML views, PDF and ePub downloads, according to the available data) and Abstracts Views on Vision4Press platform.
Data correspond to usage on the plateform after 2015. The current usage metrics is available 48-96 hours after online publication and is updated daily on week days.
Initial download of the metrics may take a while.