Solvent Development for Post-Combustion CO₂ Capture: Recent Development and Opportunities

¹ Department of Chemical Engineering, Institut Teknologi Bandung, Bandung 40132, Indonesia
² School of Chemical and Biomolecular Engineering, The University of Sydney, Sydney NSW 2006, Australia

^* Corresponding author: anggit@che.itb.ac.id

Abstract

Chemical absorption is widely regarded as the most promising technology for post-combustion CO₂ capture from large industrial emission sources with CO₂ separation from natural gas using aqueous amine solvent system having been applied since the 1930s. The use of monoethanolamine (MEA) in CO₂ absorption system possesses several drawbacks, such as high regeneration energy, high solvent loss, and high corrosion tendency. Various solvents have been developed for post-combustion CO₂ capture application including the development of aqueous solvents and phase-change solvents. Some of these alternate solvents have been reported to have better solvent properties, which could improve the CO₂ absorption system performance. This paper reviews key parameters involved in the design improvement of several chemical absorption process systems. In addition, some novel solvent systems are also discussed, for example encapsulated solvents systems. Some of the key solvent parameters that affect the capture performance, such as heat of reaction, absorption rate, solvent working capacity, solvent concentration, and solvent stability, are discussed in this paper, particularly in relation to the economic viability of the capture process. In addition, some guidelines for the future solvent development are discussed.