Kinetics of 2-chlorobiphenyl Reductive Dechlorination by Pd-fe0 Nanoparticles
School of Biological & Chemical Engineering, Taizhou Vocational & Technical College, Taizhou 318000, China
2 College of Chemical Engineering, Zhejiang University of Technology Hangzhou 310014, China
a Corresponding author: firstname.lastname@example.org
Kinetics of 2-chlorobiphenyl (2-Cl BP) catalytic reductive dechlorination by Pd-Fe0 nanoparticles were investigated. Experimental results showed that ultrafine bimetallic Pd-Fe0e nanoparticles were synthesized in the presence of 40 kHz ultrasound in order to enhance disparity and avoid agglomeration. The application of ultrasonic irradiation during the synthesis of Pd-Fe0 nanoparticles further accelerated the dechlorinated removal ratio of 2-Cl BP. Up to 95.0% of 2-Cl BP was removed after 300 min reaction with the following experimental conditions: initial 2-Cl BP concentration 10 mg L-1, Pd content 0.8 wt. %, bimetallic Pd-Fe0 nanoparticles prepared in the presence of ultrasound available dosage 7g L-1, initial pH value in aqueous solution 3.0, and reaction temperature 25°C. The catalytic reductive dechlorination of 2-Cl BP followed pseudo-first-order kinetics and the apparent pseudo-first-order kinetics constant was 0.0143 min-1.
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